Solvent dependent asymmetric hydrogenation with self-assembled catalysts: a combined catalytic, NMR- and IR-study.
نویسندگان
چکیده
For the first time the hydrogen bond based structure of self-aggregated Rh-phosphine complexes in fluorinated alcohols was directly determined, which gives a rationale for the high enantioselectivity observed in the asymmetric hydrogenation.
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ورودعنوان ژورنال:
- Chemical communications
دوره 12 شماره
صفحات -
تاریخ انتشار 2009